Benzyl 2-ethylhexyl sulfoxide

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Benzyl 2-ethyl­hexyl sulfoxide

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(Benzyl phenyl sulfoxide-κO)dichloridodiphenyl­tin(IV)

The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)], displays a distorted C(2)Cl(2)O trigonal-bipyramidal coordination environment, with a mean Sn-C distance of 2.121 (9) Å and with Sn-O = 2.331 (2) Å. The Sn(IV) atom is displaced by 0.169 (2) Å from the equatorial C(2)Cl plane towards the direction of the second axially bonded Cl atom.

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The mol-ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)(2)], has crystallographic twofold symmetry. The Sn(IV) atom is six-coordinate within a distored octa-hedral geometry defined by a C(2)Cl(2)O(2) donor set.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809044328